When most liquids freeze, the molecules line up into a rigid structure, and move closer together as they lock into place, forming a solid. This means that a given number of molecules of the same mass take up less volume. The result is that the solid is more dense than the liquid. (The same mass divided by a smaller volume gives a larger density). As these liquids freeze, the newly formed solid, still immersed in the liquid, sinks to the bottom, because the solid is more dense than the liquid it's in.
If solid water sank to the bottom as it froze, lakes and the oceans would freeze solid from the bottom up; the warmth of summer wouldn't be sufficient to melt ice at the bottom of these bodies of water. Heat from the sun would melt the top layer, which would then also evaporate; this evaporation would steal heat from the water/ice below, keeping it cold. Lakes would stay mostly frozen year-round. So if ice were denser than water, there would have been very little liquid water left after it had frozen the first time! At 4°C, water that is being cooled begins to expand, and become less dense. The closer it gets to 0°C, the less dense it gets. So a frozen lake actually has a temperature gradient, with the denser (warmer) layers near the bottom. The temperature near the bottom stays fairly constant, allowing living organisms to survive the winter. |